New Synthetic Approaches to 1,2,4,5,7-Pentoxocane Derivatives

Article abstract of DOI:10.1246/cl.1995.705

Formaldehyde O-oxide reacts with α-alkoxy-α'-hydroperoxy ethers to produce the corresponding adducts which can be cyclized under acidic conditions to yield the novel 1,2,4,5,7-pentoxocane derivatives 4a-c and 8.The structure of the crystalline 1,2,4,5,7-p