Highly like-selective [4 + 2] cycloadditions of chiral dienols: The importance of 1,3-allylic strain in the hydroxy-directed stereocontrol

DOI: 10.1021/ja00141a010

Source and publish data:

Journal of the American Chemical Society p. 9190 - 9193 (1995)

Update date:2022-08-04

Topics:

Authors:

Adam, Waldemar

Gl?ser, Jens

Peters, Karl

Prein, Michael

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Article abstract of DOI:10.1021/ja00141a010

The chiral open-chain dienols 3a,b, which possess 1,3-allylic strain due to the presence of a cis substituent, give with the dienophiles maleic anhydride (MA), N-phenyl maleimide (NPM), 4-phenyl- (PTAD), and 4-methyl-1,2,4-triazoline-3,5-dione (MTAD) the

Full text of DOI:10.1021/ja00141a010

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