Journal of the Chemical Society. Perkin transactions I p. 2849 - 2854 (1995)
Update date:2022-08-04
Topics:
Mukai, Chisato
Moharram, Sameh M.
Kataoka, Osamu
Hanaoka, Miyoji
Diisopropyl D-tartrate 7 was efficiently transformed into the hexacarbonyl dicobalt complexed aldehyde 23.A highly stereocontrolled aldol reaction of 23 with the O,S-acetal 20 in the presence of tin(IV) chloride provided, after decomplexation, the aldol adduct 21 as the sole product, which was subsequently converted into (+)-bengamide E 5.
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