Self-induced porphyrin dimer formation via unusual atropisomerization of tetraphenylporphyrin derivative

DOI: 10.1016/0040-4039(95)01819-4

Source and publish data:

Tetrahedron Letters p. 8449 - 8452 (1995)

Update date:2022-08-03

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Authors:

Kuroda, Yasuhisa

Kawashima, Ayato

Urai, Tadashi

Ogoshi, Hisanobu

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Article abstract of DOI:10.1016/0040-4039(95)01819-4

Atropisomerization of meso-tetrakis(2-carboxy-4-nonylphenyl)porphyrin 1, in nonpolar solvents such as CHCl₃ gives the αααα isomer exclusively, while the same isomerization in polar solvents such as DMSO proceeds normally. Spectroscopic investig

Full text of DOI:10.1016/0040-4039(95)01819-4

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