Tetrahedron p. 9873 - 9890 (1995)
Update date:2022-08-02
Topics:
Ihara, Masataka
Suzuki, Shuichi
Taniguchi, Takahiko
Tokunaga, Yuji
Fukumoto, Keiichiro
Reaction of β-hydroxy or acetoxy sulfones with Sml2 in the presence of HMPA caused effectively reductive elimination to provide olefins. Treatment of enol phosphates, readily synthesized from β-hydroxy sulfones via keto sulfones, under the same conditions efficiently produced mono- and disubstituted acetylenes.
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Doi:10.1016/0022-328X(95)05588-G
(1995)Doi:10.1002/recl.19951140902
(1995)Doi:10.1021/jo951264k
(1996)Doi:10.1016/0008-6215(95)00146-K
(1995)Doi:10.1021/jo981751a
(1998)Doi:10.1021/jo00130a035
(1995)