Regioselectivity of Ring-Opening Reactions of Optically Active N-Acetyl-2-Methoxycarbonylaziridine

DOI: 10.1016/0957-4166(95)00270-Y

Source and publish data:

Tetrahedron Asymmetry p. 2073 - 2080 (1995)

Update date:2022-08-03

Topics:

Authors:

Bucciarelli, Maria

Forni, Arrigo

Moretti, Irene

Prati, Fabio

Torre, Giovanni

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Article abstract of DOI:10.1016/0957-4166(95)00270-Y

(S)-(-)-N-acetyl-2-methoxycarbonylaziridine 1 undergoes easy ring-opening by Broensted acids or nucleophiles in the presence of a Lewis acid catalyst.The regioselectivity is not always exclusive, affording optically active α- and β-aminoacids.

Full text of DOI:10.1016/0957-4166(95)00270-Y

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