Synthesis of C(14',15'), dihydro derivative of the South hexacyclic steroid unit in cephalostatin 1. Part II: Spiroketal synthesis and stereochemical assignment by NMR spectroscopy

DOI: 10.1016/0040-4039(95)01805-R

Source and publish data:

Tetrahedron Letters p. 8351 - 8354 (1995)

Update date:2022-08-04

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Authors:

Bhandaru

Fuchs Fuchs

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Article abstract of DOI:10.1016/0040-4039(95)01805-R

Transformation of aldehyde 3 into 2, a C(14',15'), dihydro analog of the 'South' hexacyclic spiroketal of cephalostatin 1 1 is described. The stereochemistry of 2 was elucidated by NMR spectroscopy.

Full text of DOI:10.1016/0040-4039(95)01805-R

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