Tetrahedron p. 9899 - 9916 (1995)
Update date:2022-08-04
Topics: Conformational Properties
Hayakawa
Hirose
Noyori
Adenyldiyl trimers with different kinds of substituents on 2'-5' and 3'-5' phosphate linkages have been synthesized in a general, regiodefined manner. Examination of the 2D NMR spectra reveals that the trimers with adenyl(2'-5')adenosine linkage make a syn-anti as well as syn-syn base stack between the two adenyl bases and exist as a mixture of the two conformers.
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(2000)
