Polyhedron p. 3641 - 3648 (1995)
Update date:2022-07-30
Topics:
Jain, Vimal K.
Kannan, S.
Butcher, Ray J.
Jasinski, J. P.
The reaction of [M2Cl2(μ-Cl)2(PR3)2] with NaSeEt in 1:1 and 1:2 stoichiometry gave [M2Cl2(μ-Cl)(μ-SeEt)(PR3)2] and [M2Cl2(μ-SeEt)2(PR3)2] (M=Pd or Pt; PR3=PEt3, PBu3, PMe2Ph or PMePh2), respectively. These complexes were characterized by elemental analysis and NMR data ((1)H and (31)P). The mixed chloro/ethylselenolato bridged complexes adopt a cis configuration with phosphine trans to the bridging chloride. The molecular structure of [Pt2Cl2(μ-SeEt)2(PEt3)2] has been determined by single crystal X-ray diffraction. The complex has a planar four-membered Pt2Se2 bridge.
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Doi:10.1016/j.ejmech.2013.11.028
(2014)Doi:10.1039/c39950002233
(1995)Doi:10.1016/0040-4020(95)00771-Y
(1995)Doi:10.1021/om00012a011
(1995)Doi:10.1016/0040-4039(95)01809-V
(1995)Doi:10.1007/s12039-016-1088-y
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