Isocyanide Insertion into the Palladium-Carbon Bond of Complexes and the Reactivity of the Products toward Norbornadiene; X-Ray Crystal Structure of (bpy)Cl>

DOI: 10.1039/c39950002233

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2233 - 2234 (1995)

Update date:2022-07-30

Topics:

Authors:

Delis, Johannes G. P.

Aubel, Peter G.

Leeuwen, Piet W. N. M. van

Vrieze, Kees

Veldman, Nora

Spek, Anthony L.

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Article abstract of DOI:10.1039/c39950002233

The first examples of isocyanide insertion into methyl-palladium-chloride complexes containing 2,2'-bipyridine (bpy) and phenanthroline (phen), the X-ray crystal structure of (bpy)Cl> and the novel insertion of norbornadiene into the Pd-C(=NR)Me bond are presented; the insertion mechanism of isocyanides involves displacement of the chloride and a subsequent, slower migration of the methyl group to the precoordinated isocyanide.

Full text of DOI:10.1039/c39950002233

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