Intramolecular Diels-Alder Reactions of Silyl Acetal-tethered Trienes

DOI: 10.1016/0040-4020(95)00721-J

Source and publish data:

Tetrahedron p. 11601 - 11622 (1995)

Update date:2022-09-26

Topics:

Authors:

Ainsworth, Peter J.

Craig, Donald

Reader, John C.

Slawin, Alexandra M. Z.

White, Andrew J. P.

Williams, Dawid J.

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Article abstract of DOI:10.1016/0040-4020(95)00721-J

The synthesis and intramolecular Diels-Alder reactions of a series of silyl acetal-tethered trienes 4-9 are described.The cycloadditions show complete regioselectivity, and in all but one case give exclusively cis-fused bicyclic products.The selectivities

Full text of DOI:10.1016/0040-4020(95)00721-J

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