Chiral Oximes in Asymmetric Synthesis. Addition of Organometallic Reagents to O-(1-Phenylethyl) Aldoximes

DOI: 10.1016/0040-4020(95)00711-G

Source and publish data:

Tetrahedron p. 11473 - 11488 (1995)

Update date:2022-09-26

Topics:

Authors:

Brown, David S.

Gallagher, Peter T.

Lightfoot, Andrew P.

Moody, Christopher J.

Slawin, Alexandra M. Z.

Swann, Elizabeth

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)00711-G

Addition of Grignard and organolithium reagents to O-(1-phenylethyl) aldoximes in the presence of boron trifluoride etherate gives secondary hydroxylamines in 21-84percent yield with up to 95percent diastereomeric excess.

Full text of DOI:10.1016/0040-4020(95)00711-G

Products guided by the article

Product name:(R,E)-(+)-O-(1-phenylethyl) benzaldoxime

Cas No:172924-81-1

R&D Labs maybe for 172924-81-1

Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
jiangsu hualin chemical co.,ltd.

Contact:86-25-87787402

Address:jaingsu,china
Wuhan Jadechem International Trade Co.,Ltd.

website:http://www.jadechem-intl.com

Contact:+86-27-83527060

Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.

Contact:+86-417-2927806

Address:yingkou

Relevant to this article

Bis(NHC)-Pd-catalyzed one-pot competitive C-C*C-C, C-C*C-O, C-C*C-N, and C-O*C-N cross-coupling reactions on an aryl di-halide catalyzed by a homogenous basic ionic liquid (TAIm[OH]) under base-free, ligand-free, and solvent-free conditions

Doi:10.1039/d1nj00067e
(2021)
Doi:10.1021/ja01641a001
(1954)
Iodonium ion-assisted synthesis of tetrameric fragments corresponding to the cell wall phenolic glycolipids of Mycobacterium kansasii serovars II and IV

Doi:10.1016/0040-4020(96)00034-8
(1996)
Application of an enantiomerically pure bicyclic thiolactone in the synthesis of a farnesyl transferase inhibitor

Doi:10.1021/op700218j
(2008)
Inhibition of myo-inositol monophosphatase isoforms by aromatic phosphonates

Doi:10.1016/S0968-0896(98)00148-5
(1998)
One-pot deuteration and reduction of ketones in the synthesis of [16,16,17-²H₃]-epitestosterone

Doi:10.1135/cccc19961037
(1996)

Article Doi