Chiral Oximes in Asymmetric Synthesis. Addition of Organometallic Reagents to O-(1-Phenylethyl) Aldoximes

DOI: 10.1016/0040-4020(95)00711-G

Source and publish data:

Tetrahedron p. 11473 - 11488 (1995)

Update date:2022-09-26

Topics:

Authors:

Brown, David S.

Gallagher, Peter T.

Lightfoot, Andrew P.

Moody, Christopher J.

Slawin, Alexandra M. Z.

Swann, Elizabeth

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Article abstract of DOI:10.1016/0040-4020(95)00711-G

Addition of Grignard and organolithium reagents to O-(1-phenylethyl) aldoximes in the presence of boron trifluoride etherate gives secondary hydroxylamines in 21-84percent yield with up to 95percent diastereomeric excess.

Full text of DOI:10.1016/0040-4020(95)00711-G

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Product name:(R,E)-(+)-O-(1-phenylethyl) benzaldoxime

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