Tetrahedron Letters p. 8367 - 8370 (1995)
Update date:2022-08-03
Topics:
Wladislaw
Marzorati
Torres Russo
Zaim
Di Vitta
The reaction of some isopropylsulfonyl α-mono and disubstituted esters with KOH/t-BuOH/CCl4 is reported. For the α,α-dialkyl and α-monoaryl substituted derivatives the key step of this reaction is proposed to be the decarboxylative 1,3-displacement in the chlorinated intermediates.
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