Stereochemistry in Reactions of Chiral Cyclic Allylsilanes with (Ethoxycarbonyl)nitrene. A New Route to Chiral N-substituted Allylamines

DOI: 10.1016/0040-4039(95)01734-Y

Source and publish data:

Tetrahedron Letters p. 8295 - 8298 (1995)

Update date:2022-08-05

Topics:

Authors:

Loreto, Maria Antonietta

Tardella, Paolo A.

Tofani, Daniela

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01734-Y

The S_E' reactions of chiral cyclic allylsilanes with (ethoxycarbonyl)nitrene generated by α-elimination of NsONHCO2Et with Et3N permit us to obtain chiral N-substituted allylic amines in good diastereomeric excess when stereoelectronic and conf

Full text of DOI:10.1016/0040-4039(95)01734-Y

Products guided by the article

Product name:(1S,5R)-ethyl 5-methylcyclohex-2-enyl carbamate

Cas No:173163-36-5

R&D Labs maybe for 173163-36-5

JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
CHEMINN LTD.

website:http://www.cheminn.com/

Contact:86-531-67875205

Address:No.9-2,South of Shanda Road, Jinan ,China
Shanghai Dano Pharmaceutical Co.,Ld.(expird)

Contact:+86-592-6266840

Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Jiangsu Seed Chem Co.,Ltd.

Contact:86-513-84128750/13773795976

Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China

Relevant to this article

2-(Quinuclidin-3-yl)pyrido[4,3-b]indol-1-ones and isoquinolin-1-ones. Potent conformationally restricted 5-HT₃ receptor antagonists

Doi:10.1021/jm00070a008
(1993)
Chemistry of 1-alkoxy-1-glycosyl radicals: The manno- and rhamnopyranosyl series. Inversion of α- to β-pyranosides and the fragmentation of anomeric radicals

Doi:10.1021/jo951194h
(1996)
Reaction of thiolato-ligands with rhenium hydrides - III. Complexes of mercaptopyridines. The syntheses and X-Ray crystal structures of [ReHF(2-SC₅H₄N)₂(PMe₂Ph) ₂]BF₄ and [ReH(2-SC₅

Doi:10.1016/0277-5387(95)00304-4
(1996)

Stereoselective synthesis of β-mannopyranosides via the temporary silicon connection method

Doi:10.1021/ja9532291
(1996)
tert-butyl-substituted tripyrranes: Insights into the steric and conformational factors that influence porphyrinoid ring formation in the "3 + 1" methodology

Doi:10.1021/jo0207628
(2003)
Doi:10.1039/j39670002041
(1967)

Article Doi