Stereochemistry in Reactions of Chiral Cyclic Allylsilanes with (Ethoxycarbonyl)nitrene. A New Route to Chiral N-substituted Allylamines

DOI: 10.1016/0040-4039(95)01734-Y

Source and publish data:

Tetrahedron Letters p. 8295 - 8298 (1995)

Update date:2022-08-05

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Authors:

Loreto, Maria Antonietta

Tardella, Paolo A.

Tofani, Daniela

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Article abstract of DOI:10.1016/0040-4039(95)01734-Y

The S_E' reactions of chiral cyclic allylsilanes with (ethoxycarbonyl)nitrene generated by α-elimination of NsONHCO2Et with Et3N permit us to obtain chiral N-substituted allylic amines in good diastereomeric excess when stereoelectronic and conf

Full text of DOI:10.1016/0040-4039(95)01734-Y

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