
Tetrahedron Letters p. 217 - 220 (1996)
Update date:2022-07-30
Topics:
Nakata, Tadashi
Nomura, Sumihiro
Matsukura, Hiroko
Morimoto, Masamichi
The 7, 7-membered CD ring system of hemibrevetoxin B was stereoselectively synthesized. The crucial steps involve the Sharpless asymmetric epoxidation, cyclization to the 6-membered ether, and double rearrangement of the 6, 6-membered bicyclic ether with
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(1996)