Tetrahedron Letters p. 213 - 216 (1996)
Update date:2022-07-30
Topics:
Nakata
Nomura
Matsukura
Six- and seven-membered ether rings were stereoselectively synthesized based on the rearrangement of the cyclic ether with the simultaneous ring expansion. Treatment of ether having a mesylate or bromide group as the leaving group on the side chain with Zn(OAc)2 or AgOAc stereoselectively produced the ring expanded ether in good yield.
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