Acta Crystallographica, Section C: Crystal Structure Communications p. 330 - 333 (1996)
Update date:2022-08-03
Topics:
Mueller, Ulrich
Siekmann, Juergen
Frenzen, Gerlinde
Tetraphenylphosphonium pentachlorostannate contains trigonal-bipyramidal [SnCl5]- ions. It is isotypic with PPh4[Sn(CH3)Cl4]; however, the published space group of the latter is corrected from P2 to P2/n. In the hydrate the [SnCl5(H2O)]- ions have a distorted octahedral configuration. The packing principle is the same for both compounds and corresponds to the known arrangement in tetraphenylphosphonium compounds with PPh4+ ions stacked in columns in the c direction.
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