Catalytic triple carbonylation of olefins. Enantioselective synthesis of 2-oxoglutarates

DOI: 10.1016/0022-328X(95)05654-8

Source and publish data:

Journal of Organometallic Chemistry p. 177 - 180 (1996)

Update date:2022-08-02

Topics:

Authors:

Sperrle, Martin

Consiglio, Giambattista

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(95)05654-8

A new carbonylation reaction, namely "triple carbonylation" of olefins catalysed by cationic palladium complexes to substituted 2-oxoglutarates, has been developed. Even though the chemoselectivity is not high, this reaction allows a one-step synthesis of

Full text of DOI:10.1016/0022-328X(95)05654-8

Products guided by the article

Product name:Pentanedioic acid, 2-oxo-4-(phenylmethyl)-, dimethyl ester

Cas No:174678-99-0

R&D Labs maybe for 174678-99-0

Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Wuxi Pharma-Trading Import & Export Co.,Ltd.

Contact:+86-510-82304590 82716390

Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Pengchen New Material Technology Co., Ltd.

Contact:+86-512-63680537

Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Zhengzhou Xinlian Chemical Tech Co. ,Ltd

Contact:0371-65771781 021-52042910

Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai

Relevant to this article

Synthesis of enantiomerically pure anti-aldols: A highly stereoselective ester-derived titanium enolate aldol reaction

Doi:10.1021/ja9539148
(1996)
Electronic structure of Eu@C₆₀ studied by XANES and UV-VIS absorption spectra

Doi:10.1016/S0009-2614(99)01309-3
(2000)
Versatile 2-fluoroacrylic building blocks for the synthesis of fluorinated heterocyclic compounds

Doi:10.1016/0040-4020(96)00084-1
(1996)
Two-carbon bridge substituted cocaines: Enantioselective synthesis, attribution of the absolute configuration and biological activity of novel 6- and 7-methoxylated cocaines

Doi:10.1016/S0014-827X(99)00027-0
(1999)
Chemospecific synthesis of 2-acetoxyindole-3-carbonitriles catalyzed by Cu(acac)₂

Doi:10.1007/s11172-016-1509-6
(2016)
Growth inhibition of Cryptococcus neoformans by 2-(1-piperazinyl)-5-(1,2-diarylethyl)-4,6-dichloropyrimidines: Synthesis and in vitro studies

Doi:10.1016/S0223-5234(96)80010-9
(1996)

Article Doi