Synthesis, spectra and electrochemistry of Ru(III) complexes with tetradentate schiff bases

Article abstract of DOI:10.1080/00945719608004245

A series of low-spin ruthenium(III) complexes of the type [RuX(EPh₃)(LL')] (X = Cl, Br; E = P, As; LL' = Salen, Salpn and Saldien) have been synthesised by reacting [RuCl₃(PPh₃)₃], [RuCl₃(AsPh₃)₃], [RuBr₃(AsPh₃)₃] or [RuBr₃(PPh₃)₂(MeOH)] with tetradentate Schiff bases such as bis(salicylaldehyde)ethylenediimine (H₂-Salen), bis(salicylaldehyde)propylenediimine (H₂-Salpn) and bis(salicylaldehyde)diethylenetriimine (H₂-Saldien). All complexes have been characterized by elemental analyses, IR and electronic spectra, EPR, magnetic moment and cyclic voltammetric data.

Full text of DOI:10.1080/00945719608004245

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Synthesis and Reactivity in
Inorganic and Metal-Organic
Chemistry
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Synthesis, Spectra and
Electrochemistry of
Ru(III) Complexes with
Tetradentate Schiff Bases
R. Ramesh a , P. K. Suganthy a & K. Natarajan a
a Department of Chemistry, Bharathiar
University, Coimbatore, 641046, India
Published online: 23 Aug 2006.
To cite this article: R. Ramesh , P. K. Suganthy & K. Natarajan (1996): Synthesis,
Spectra and Electrochemistry of Ru(III) Complexes with Tetradentate Schiff
Bases, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 26:1,
47-60
To link to this article: http://dx.doi.org/10.1080/00945719608004245
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