A convenient preparation of pentafluorophenyl( fluoro) silanes: Reactivity of pentafluorophenyltrifluorosilane

DOI: 10.1016/0022-328X(95)05676-G

Source and publish data:

Journal of Organometallic Chemistry p. 155 - 164 (1996)

Update date:2022-08-04

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Authors:

Frohn Frohn

Giesen Giesen

Klose Klose

Lewin Lewin

Bardin Bardin

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Article abstract of DOI:10.1016/0022-328X(95)05676-G

Pentafluorophenyl(fluoro)silanes (C₆F₅)_nSiF_4-n (n = 1, 2) were prepared from the corresponding ethoxysilanes by sequential chlorodeethoxylation with SOCl₂ and fluoridation of chlorosilanes with SbF₃. The conversion of C₆F₅Si(OEt)₃ and C₆F₅SiCl₃ into C₆F₅SiF₃ with anhydrous HF was described. Some reactions of C₆F₅SiF₃ with electrophiles and nucleophiles were studied.

Full text of DOI:10.1016/0022-328X(95)05676-G

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