Tetrahedron p. 1723 - 1734 (1996)
Update date:2022-07-31
Topics:
Tome, Augusto C.
Cavaleiro, Jose A. S.
Storr, Richard C.
Pyrimidone fused sulfones 5-7 were obtained from the reaction of amidines with 3-methoxycarbonyl-4-oxotetrahydrothiophene followed by N-methylation and oxidation with mCPBA. On heating in solution at 150°C, extrusion of SO2 occurred to give the highly reactive 5,6-dimethylenepyrimidin-4-ones which were intercepted in situ in Diels-Alder reactions to give the adducts 24-28 and in conjugate addition reactions with thiol nucleophiles to give the thioethers 29 and 30.
View MoreChengdu Biopurify Phytochemicals Ltd.
website:http://www.phytopurify.com
Contact:+86-28-82633397
Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
China Synchem Technology Co.,Ltd
website:http://www.cnsynchem.com
Contact:+86-0552-4929311
Address:No.217 Daqing Road
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Pengchen New Material Technology Co., Ltd.
Contact:+86-512-63680537
Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
Contact:86-21-57725962
Address:shanghai
Doi:10.1021/jo0015927
(2001)Doi:10.1021/jo050465d
(2005)Doi:10.1021/ja953146k
(1996)Doi:10.1080/00958972.2017.1364374
(2017)Doi:10.1039/b007077g
(2001)Doi:10.1016/0040-4039(95)02411-5
(1996)
