Substituent effects on intramolecular dipolar cycloadditions: The gem-dicarboalkoxy effect

DOI: 10.1016/0040-4039(95)02196-5

Source and publish data:

Tetrahedron Letters p. 451 - 454 (1996)

Update date:2022-07-31

Topics:

Authors:

Jung, Michael E.

Vu, Binh T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02196-5

A gem-dicarboalkoxy effect (rel. rate > 20) has been measured and good diastereoselectivity (~ 9:1) has been seen for the intramolecular dipolar cycloaddition of 3-substituted 5-hexenyl nitrile oxides.

Full text of DOI:10.1016/0040-4039(95)02196-5

Products guided by the article

Product name:3-Phenyl-hex-5-enenitrile N-oxide

Cas No:174866-60-5

R&D Labs maybe for 174866-60-5

Nanyang Tianhua pharmaceutical Co.,Ltd.

Contact:+8618639816203

Address:Longsheng Industrial Park
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.

Contact:13861062998

Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China

Relevant to this article

Organophosphorus chemistry. Part 1: The synthesis of alkyl methylphosphonic acids

Doi:10.1039/b007077g
(2001)
Total synthesis of herbertenediol, an isocuparane sesquiterpene isolated from liverworts

Doi:10.1016/0040-4039(95)02411-5
(1996)
A direct asymmetric synthesis of juglomycin A

Doi:10.1021/jo952077p
(1996)
Generation of 6-alkylidene/benzylidene-3,6-dihydropyrazin-2(1H)-ones by reaction of 6-bromomethylpyrazin-2(1H)-ones with methoxide and further conversion into specific piperazine-2,5-diones and pyrazin-2(1H)-ones

Doi:10.1039/p19960000231
(1996)
Ribosylation of the base residue of inosine derivatives by phase-transfer catalysis

Doi:10.1080/07328319608002366
(1996)
Room Temperature Fluorination of 1,3-Diketones and Enol Acetates with Xenon Difluoride

Doi:10.1039/c39800000759
(1980)

Article Doi