Substituent effects on intramolecular dipolar cycloadditions: The gem-dicarboalkoxy effect

DOI: 10.1016/0040-4039(95)02196-5

Source and publish data:

Tetrahedron Letters p. 451 - 454 (1996)

Update date:2022-07-31

Topics:

Authors:

Jung, Michael E.

Vu, Binh T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02196-5

A gem-dicarboalkoxy effect (rel. rate > 20) has been measured and good diastereoselectivity (~ 9:1) has been seen for the intramolecular dipolar cycloaddition of 3-substituted 5-hexenyl nitrile oxides.

Full text of DOI:10.1016/0040-4039(95)02196-5

Products guided by the article

Product name:3-Phenyl-hex-5-enenitrile N-oxide

Cas No:174866-60-5

R&D Labs maybe for 174866-60-5

Phantom-pharma

Contact:

Address:
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang
Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0
Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou

Relevant to this article

Organophosphorus chemistry. Part 1: The synthesis of alkyl methylphosphonic acids

Doi:10.1039/b007077g
(2001)
Total synthesis of herbertenediol, an isocuparane sesquiterpene isolated from liverworts

Doi:10.1016/0040-4039(95)02411-5
(1996)
A direct asymmetric synthesis of juglomycin A

Doi:10.1021/jo952077p
(1996)
Generation of 6-alkylidene/benzylidene-3,6-dihydropyrazin-2(1H)-ones by reaction of 6-bromomethylpyrazin-2(1H)-ones with methoxide and further conversion into specific piperazine-2,5-diones and pyrazin-2(1H)-ones

Doi:10.1039/p19960000231
(1996)
Ribosylation of the base residue of inosine derivatives by phase-transfer catalysis

Doi:10.1080/07328319608002366
(1996)
Room Temperature Fluorination of 1,3-Diketones and Enol Acetates with Xenon Difluoride

Doi:10.1039/c39800000759
(1980)

Article Doi