Chemical and Pharmaceutical Bulletin p. 252 - 254 (1996)
Update date:2022-08-03
Topics:
Miyashita
Suzuki
Okumura
Higashino
The treatment of 2-benzyl-1,2-diphenyl-2-hydroxyethanone (3a, benzylbenzoin) with potassium cyanide in DMF gave deoxybenzoin (4a). The formation of deoxybenzoin (4a) proceeds through retro-benzoin condensation by catalytic action of cyanide ion. Similarly, retro-benzoin condensation applied to several substituted benzoins 3 resulted in the formation of the corresponding ketones 4 in excellent yields.
View MoreLonghui qunfeng Chemical Co., Ltd
Contact:86-731-82173407
Address:South-east Industrial Park, Longhui County, Hunan Province, China
Zhejiang Sanmei Chemical Industry Co., Ltd
Contact:86-579-87633213
Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
website:https://www.sinoshiny.com/products
Contact:+86-20-62802632;62802633
Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Contact:+44 (0)2036089360-31
Address:Chanceryhouse,Chancery Lan
Beijing Mashi Fine Chemical Co.,Ltd.
Contact:+86-10-61271592
Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Doi:10.1021/jo010937y
(2002)Doi:10.1016/j.tet.2018.01.048
(2018)Doi:10.1021/jo00170a049
(1983)Doi:10.1016/S0022-1139(00)80466-2
(1993)Doi:10.1016/S0040-4020(01)99007-6
(1962)Doi:10.1021/ja017575w
(2002)
