Journal of Organometallic Chemistry p. 205 - 213 (1991)
Update date:2022-09-26
Topics:
Chipperfield, John R.
Clark, Stephen
Webster, David E.
Yusof, Halimahton
Rate coefficients are reported for the cleavage by halogens of tin-transition-metal bonds in compounds containing two or more such bonds.Bond reactivity with iodine is in the order Sn-Co ca.Sn-Fe above Sn-Mo ca.Sn-W above Sn-Mn.Rates of halogenation of compounds containing three tin-transition-metal bonds show that a subtle balance between steric and electronic effects determines bond reactivity.
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