Reactivity of Main-Group-transition-metal bonds IX*. The kinetics of iodination of compounds containing two or more tin-transition-metal bonds

DOI: 10.1016/0022-328X(91)86405-F

Source and publish data:

Journal of Organometallic Chemistry p. 205 - 213 (1991)

Update date:2022-09-26

Topics:

Authors:

Chipperfield, John R.

Clark, Stephen

Webster, David E.

Yusof, Halimahton

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Article abstract of DOI:10.1016/0022-328X(91)86405-F

Rate coefficients are reported for the cleavage by halogens of tin-transition-metal bonds in compounds containing two or more such bonds.Bond reactivity with iodine is in the order Sn-Co ca.Sn-Fe above Sn-Mo ca.Sn-W above Sn-Mn.Rates of halogenation of compounds containing three tin-transition-metal bonds show that a subtle balance between steric and electronic effects determines bond reactivity.

Full text of DOI:10.1016/0022-328X(91)86405-F

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