Allylated ketosulphides of benzothiazole as intermediates for stereoselective synthesis of allyl ketones, allyl thiiranes and dienes

DOI: 10.1016/0040-4020(95)01030-0

Source and publish data:

Tetrahedron p. 2155 - 2166 (1996)

Update date:2022-07-29

Topics:

Authors:

Calo, Vincenzo

Fiandanese, Vito

Nacci, Angelo

Volpe, Angela

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Article abstract of DOI:10.1016/0040-4020(95)01030-0

α-Ketosulphides of benzothiazol 1 react with allylic carbonates in the presence of palladium acetate in dichloromethane under mild conditions affording α- and α,α-diallylated ketosulphides 2 in high yields. Reductive desulphurization of 2a-d with tributyl

Full text of DOI:10.1016/0040-4020(95)01030-0

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