Allylated ketosulphides of benzothiazole as intermediates for stereoselective synthesis of allyl ketones, allyl thiiranes and dienes

DOI: 10.1016/0040-4020(95)01030-0

Source and publish data:

Tetrahedron p. 2155 - 2166 (1996)

Update date:2022-07-29

Topics:

Authors:

Calo, Vincenzo

Fiandanese, Vito

Nacci, Angelo

Volpe, Angela

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(95)01030-0

α-Ketosulphides of benzothiazol 1 react with allylic carbonates in the presence of palladium acetate in dichloromethane under mild conditions affording α- and α,α-diallylated ketosulphides 2 in high yields. Reductive desulphurization of 2a-d with tributyl

Full text of DOI:10.1016/0040-4020(95)01030-0

Products guided by the article

Product name:(E)-2-(Benzothiazol-2-ylsulfanyl)-1,5-diphenyl-pent-4-en-1-one

Cas No:175600-60-9

R&D Labs maybe for 175600-60-9

Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
Dalian Ruiying Technology Co., Ltd.

Contact:0411-86907150

Address:6 Xiangxiu street, Xigang District
Reliability Assessment Solutions (Changhzou) Co., Ltd.

Contact:86-519-85607515

Address:RM 601-603 BD1 Fuchen Mansion, 8 Taihu East RD, Xinbei District, Changhou, Jiangsu 213022, China
JiangXi Keyuan Biopharma Co., LTD.

Contact:+86-563-6833666

Address:Guangde Fine Chemical Zone, Anhui Province, China
Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County

Relevant to this article

Diastereoselective synthesis of (1S,2S,3R,6S) 3-chloro-3-methyl-6-isopropenyl-1,2-cyclohexanediol via Prins reaction induced by zinc and trimethylsilyl chloride

Doi:10.1016/0040-4020(96)00167-6
(1996)
Artificial multi-enzyme networks for the asymmetric amination of sec-alcohols

Doi:10.1002/chem.201202666
(2013)
Chemo- and Diastereoselective Synthesis of N-Propargyl Oxazolidines through a Copper-Catalyzed Domino A³ Reaction

Doi:10.1021/acs.joc.8b03244
(2019)
Doi:10.1007/BF00909453
(1965)
The unexpected formation of a 2,2′-DI(N-ethyl-acetamino)substituted diphenyl disulfane on oxidation of 3-ethyl-2-methylbenzothiazolium tetrafluoroborate

Doi:10.1080/10426500307848
(2003)
IODINATION OF PHENOLS USING CHLORAMINE T AND SODIUM IODIDE

Doi:10.1016/S0040-4039(00)94774-9
(1985)

Article Doi