Tetrahedron Letters p. 1373 - 1376 (1997)
Update date:2022-07-29
Topics:
Gotzhein, Frank
Kirmse, Wolfgang
2-Allyloxyphenylcarbenes (8) undergo intramolecular addition (→ 9) and (formal) C-H insertion (→ 11) competitively. Stereochemical labels indicate that 11 and major amounts of 9 arise from triplet 8. The intermolecular O-H insertion of singlet 8 with meth
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