Chemoselectivity in the rhodium(II) acetate catalysed decomposition of α-diazo-β-keto-γ,δ-alkenyl-δ-aryl compounds: Aromatic C-H insertion reaction or Wolff rearrangement-electrocyclization

DOI: 10.1016/0040-4020(96)00581-9

Source and publish data:

Tetrahedron p. 10455 - 10472 (1996)

Update date:2022-07-29

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Authors:

Collomb, Didier

Chantegrel, Bernard

Deshayes, Christian

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Article abstract of DOI:10.1016/0040-4020(96)00581-9

The rhodium(II) acetate catalysed decomposition of α-diazo-β-keto-γ,δ-alkenyl phosphonates 1 substituted in the δ-position by an aryl group gave rise to mixtures of isomeric hydroxynaphthalenephosphonates, 3 resulting from a Wolff rearrangement-electrocyc

Full text of DOI:10.1016/0040-4020(96)00581-9

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