Chemical Communications p. 261 - 262 (1996)
Update date:2022-08-02
Topics:
Morran, Paul D.
Mawby, Roger J.
Wilson, Giles D.
Moore, Madeleine H.
The methyl-substituted ruthenafuran 5 rearranges at room temperature by dismantling and reassembly of the five-membered ring, yielding 7 and then 8: the conversion is catalysed by Me3CNH2; in contrast Me3CNH2 attacks 2, the phenyl analogue of 5, to give a stable non-cyclic aminocarbene complex 3.
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