Synthesis, nucleophilic attack on, and rearrangement of cationic ruthenafurans: X-ray crystal structures of [Ru(CO)2{C(Ph)NHCMe3}(CH2CO 2Et)(PMe2Ph)2][PF6] and [Ru(CO)2{C(Me)=CHC(O)OEt}(PMe2Ph)2][PF 6]

DOI: 10.1039/CC9960000261

Source and publish data:

Chemical Communications p. 261 - 262 (1996)

Update date:2022-08-02

Topics:

Authors:

Morran, Paul D.

Mawby, Roger J.

Wilson, Giles D.

Moore, Madeleine H.

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Article abstract of DOI:10.1039/CC9960000261

The methyl-substituted ruthenafuran 5 rearranges at room temperature by dismantling and reassembly of the five-membered ring, yielding 7 and then 8: the conversion is catalysed by Me₃CNH₂; in contrast Me₃CNH₂ attacks 2, the phenyl analogue of 5, to give a stable non-cyclic aminocarbene complex 3.

Full text of DOI:10.1039/CC9960000261

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Product name:Ru(CO)3(CH₃)(P(CH₃)2C₆H₅)2⁽¹⁺⁾*PF₆^(1-) = [Ru(CO)3(CH₃)(P(CH₃)2C₆H₅)2]PF₆

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