
Inorganic Chemistry p. 419 - 422 (1968)
Update date:2022-08-05
Topics:
Wells, Richard L.
Collins, Alva L.
The reactions of bis(trimethylsilyl)aminotrimethylsilylaminochloroborane with ammonia, various amines, methyl alcohol, and n-butyllithium have been studied. A number of unsymmetrical trisaminoboranes, a methoxy compound, and a compound containing a four-membered boron-nitrogen ring have been prepared. Also, a possible mechanism for the formation of aminobis(trimethylsilyl)aminotrimethylsilylaminoborane from trichloroborane and excess hexamethyldisilazane is discussed.
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