REACTION OF NUCLEOPHILES WITH ELECTRON ACCEPTORS BY SN2 OR SINGLE ELECTRON TRANSFER (S.E.T.) MECHANISMS: THIOLATES AND 2-HALOMETHYL-5-NITROFURANS.

DOI: 10.1016/S0040-4039(01)91275-4

Source and publish data:

Tetrahedron Letters p. 4979 - 4982 (1984)

Update date:2022-07-30

Topics:

Authors:

Beadle, Charles D.

Bowman, W. Russell

Prousek, Josef

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Article abstract of DOI:10.1016/S0040-4039(01)91275-4

Thiolates react with 2-halomethyl-5-nitrofurans to yield 5-nitrofurfuryl sulphides by a S_N2(C) mechanism, and disulphides and 2-methyl-5-nitrofuran by a S_N2(X) mechanism.

Full text of DOI:10.1016/S0040-4039(01)91275-4

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