Reductive Disproportionation of Carbon Dioxide by Dianionic Carbonylmetalates of the Transition Metals

DOI: 10.1021/ja00244a017

Source and publish data:

Journal of the American Chemical Society p. 2956 - 2962 (1987)

Update date:2022-09-26

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Authors:

Lee, Gary R.

Maher, John M.

Cooper, N. John

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Article abstract of DOI:10.1021/ja00244a017

Carbon dioxide reacts readily with M2 (M=Li, Na, K, M'=W; M=K, M'=Cr, Mo, W) to give the corresponding group 6 hexacarbonyls and alkali metal carbonates.The reaction of Li2 with excess 13CO2 at -78 deg C gives , con

Full text of DOI:10.1021/ja00244a017

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