Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray Structure of [Ru(PHFCH2BUt)Cl(CO)(CNC6H3Me 2-2,6)(PPh3)2]BF4·CH 2Cl2</su

DOI: 10.1039/CC9960001895

Source and publish data:

Chemical Communications p. 1895 - 1896 (1996)

Update date:2022-08-05

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Authors:

Bedford, Robin B.

Hibbs, David E.

Hill, Anthony F.

Hursthouse, Michael B.

Malik, K. M. Abdul

Jones, Cameron

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Article abstract of DOI:10.1039/CC9960001895

The reaction of [Ru(P=CHBu^t)Cl(CO)(CNC₆H₃Me ₂-2,6)(PPh₃)₂] with HBF₄ provides, rapidly and reversibly, the phosphaalkene complex [RU(HP=CHBu^t)Cl(CO)(CNC₆H View More

Full text of DOI:10.1039/CC9960001895

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Product name:RuCl(CO)(PHCHC(CH₃)3)(CNC₆H₃(CH₃)2)(P(C₆H₅)3)2⁽¹⁺⁾*BF₄^(1-) = [RuCl(CO)(PHCHC(CH₃)3)(CNC₆H₃(CH₃)2)(P(C₆H₅)3)2]BF₄

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