Synthesis, characterization, and molecular structure of the first closo-hydrido complexes of osmium with carborane ligands: Closo-3,3-(PPh3)2-3-H-3-Cl-3,1,2-OsC2B 9H11 and closo-3,3-(PPh3)<

DOI: 10.1021/om950967p

Source and publish data:

Organometallics p. 2619 - 2623 (1996)

Update date:2022-07-29

Topics:

Authors:

Chizhevsky, Igor T.

Petrovskii, Pavel V.

Sorokin, Pavel V.

Bregadze, Vladimir I.

Dolgushin, Fedor M.

Yanovsky, Aleksandr I.

Struchkov, Yuri T.

Demonceau, Albert

Noels, Alfred F.

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Novel 12-vertex closo-hydridometallacarboranes 3,1,2-[(PPh₃)₂OsHXC₂B₉H ₁₁] (1a,b: X = Cl, H) and 3,1,2-[(PPh₃)₂OsH₂-1,2-Me₂C ₂B₉H

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