Tetrahedron Asymmetry p. 771 - 777 (1996)
Update date:2022-08-05
Topics: TLC Lipase Acylation Regioselectivity Diastereoselectivity Flash chromatography Characterization Purification Lipase Enzyme Organic Solvent Buffer Solution Esterification Reaction Adjust pH Incubation Monitoring Work-Up Product Isolation
Colombo, Diego
Ronchetti, Fiamma
Scala, Antonio
Taino, Ida M.
Toma, Lucio
2-O-β-D-glucopyranosylglycerol was submitted to acylation using Pseudomonas cepacia lipase as catalyst and 2,2,2-trifluoroethyl esters of various long chain carboxylic acids as acyl carriers. Monoacylation was easily accomplished with preferred formation of the (2S)-1-O-acyl derivatives in reactions showing high regio- and diastereoselectivity.
View MoreXinji City Taida Sinopec Co., Ltd.
Contact:0086-311-85341278
Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Contact:13813902930 025-52714267
Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
KINHENG CHEMICAL(SHANGHAI)CO., LTD.
Contact:+8621-60490170
Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Contact:+86-913-2223392
Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
website:http://www.maisonchem.com.cn
Contact:0086-311-83833777
Address:Leitou industrial district, xinji, shijiazhuang city, hebei province,
Doi:10.1021/jm00303a030
(1969)Doi:10.1016/0040-4020(96)00285-2
(1996)Doi:10.1021/jo960134o
(1996)Doi:10.1039/c39920001753
(1992)Doi:10.1016/0040-4020(96)00869-1
(1996)Doi:10.1021/jm9805337
(1999)
