Bulletin of the Chemical Society of Japan p. 1117 - 1124 (1996)
Update date:2022-08-04
Topics:
Kawanami, Yukio
Yamamoto, Keiji
Rh(I)-catalyzed dehydrogenative silylation was selectively carried out by using divinylsilanes and half an equimolar amount of trialkylsilanes under ambient conditions to give 1,2-disilylethene and ethylvinylsilane derivatives in equimolar amounts. The mechanistic aspects for the dehydrogenative silylation were discussed in terms of the consecutive migratory insertions of the alkene moiety into both Rh-Si and Rh-H bonds which are formed by an oxidative addition of the hydrosilane to the Rh(I) catalyst precursor.
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