Tetrahedron Letters p. 2573 - 2576 (1996)
Update date:2022-08-02
Topics:
Imogai, Hassan
Petit, Yves
Larcheveque, Marc
Sigmatropic rearrangement of trichloracetimidates derived from syn monoprotected allylic diols 3 resulting from the condensation of vinylalanes or cuprates with α-alkoxyaldehydes afforded diastereomerically pure allylic amines 6. The oxidative cleavage of these amines allowed the access to α,α-disubstituted α-aminoacids in high enantiomeric purity.
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