Journal of the Chemical Society, Dalton Transactions p. 1809 - 1813 (1996)
Update date:2022-07-29
Topics:
Hill, Geoffrey S.
Rendina, Louis M.
Puddephatt, Richard J.
Treatment of [PtCl(Me)(dbbipy)] or [PtCl2(dbbipy)] (dbbipy = 4,4′-di-tert-butyl-2,2′-bipyridine) with AgX (X = SO3CF3 or O2CCF3) gave the complexes [PtMe(SO3CF3)(dbbipy)] 1, [Pt(SO3CF3)2(dbbipy)] 2 and [Pt(O2CCF3)2(dbbipy)] 5. The complexes [PtCl(SO3CF3)(dbbipy)] 3 and [PtMe(O2CCF3)(dbbipy)] 4 were prepared by the addition of HX to [PtCl2(dbbipy)] or [PtMe2(dbbipy)], respectively. Complex 1 reacted with CO to give the cationic carbonyl complex [PtMe(CO)(dbbipy)][SO3CF3] 6a, which reacted with NEt2H to give an equilibrium with the corresponding carbamoyl complex [Pt(CONEt2)Me(dbbipy)] 7. In the first example of alkyl-ligand abstraction from a late-transition-metal complex by the powerful Lewis acid B(C6F5)3, the complexes [PtMeL(dbbipy)][BMe(C6F5)3] (L = CO 6b or C2H4 8) were readily prepared from [PtMe2(dbbipy)] and B(C6F5)3 in the presence of L.
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD
website:http://www.fengrunhuagong.com
Contact:+86-536-7869976
Address:Changyi Coastal Economic Development Zone
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Contact:+86-021-6989-5597
Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
zhejiang huangyan wanfeng pharm chem co.ltd
Contact:+86-576- 84160728
Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Doi:10.1021/ja01133a529
(1952)Doi:10.1016/j.molstruc.2003.12.024
(2004)Doi:10.1016/S0022-328X(00)80074-1
(1969)Doi:10.3987/COM-99-8583
(1999)Doi:10.1002/(SICI)1521-4184(19994)332:4<124::AID-ARDP124>3.0.CO;2-G
(1999)Doi:10.1039/b002374o
(2000)
