Photochemical intermolecular C-H and C-F insertion of rhodium into pentafluoroanisole to generate a metallacycle; conversion to a cyclic carbene complex

DOI: 10.1039/CC9960000961

Source and publish data:

Chemical Communications p. 961 - 962 (1996)

Update date:2022-07-31

Topics:

Authors:

Ballhorn, Michael

Partridge, Martin G.

Perutz, Robin N.

Whittlesey, Michael K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/CC9960000961

Irradiation of [(η⁵-C₅H₅)Rh(PMe₃XC ₂H₄)] in pentafluoroanisole generates the metallacycle [(η⁵-C₅H₅)(PMe₃)RhCH ₂OC₆F₄]; reaction of this complex with 1 equiv. of Ph₃C⁺PF₆⁺ at 220 K generates [(η⁵-C₅H₅)(PMe₃)Rh=C(H)OC ₆F₄]PF₆.

Full text of DOI:10.1039/CC9960000961

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Rh(C₅H₅)(P(C₆H₅)3)(C₆F₄OCH₂)]

Cas No:177595-77-6

R&D Labs maybe for 177595-77-6

Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road
Shenyang NovPharm Technology Co., Ltd.

Contact:.+86-24-24165786

Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist

Relevant to this article

Multigram-scale flow synthesis of the chiral key intermediate of (-)-paroxetine enabled by solvent-free heterogeneous organocatalysis

Doi:10.1039/c9sc04752b
(2019)
D-mannitol as the chiral source for the EPC synthesis of both enantiomers of 3-ethoxycarbonyl-4-hydroxy-2-isoxazolines and highly functionalized tricyclic systems

Doi:10.1021/jo980941i
(1998)
Chiral and Regenerable NAD(P)H Models Enabled Biomimetic Asymmetric Reduction: Design, Synthesis, Scope, and Mechanistic Studies

Doi:10.1021/acs.joc.9b03054
(2020)
Doi:10.1016/S0040-4039(00)75550-X
(1968)
Development of 2,3,5-triaryl-1H-pyrroles as estrogen receptorα selective ligands

Doi:10.1002/cmdc.201100283
(2011)
New analogues of butylated hydroxytoluene as anti-inflammatory and antioxidant agents

Doi:10.1016/j.bmc.2006.04.030
(2006)

Article Doi