Photochemical intermolecular C-H and C-F insertion of rhodium into pentafluoroanisole to generate a metallacycle; conversion to a cyclic carbene complex

DOI: 10.1039/CC9960000961

Source and publish data:

Chemical Communications p. 961 - 962 (1996)

Update date:2022-07-31

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Authors:

Ballhorn, Michael

Partridge, Martin G.

Perutz, Robin N.

Whittlesey, Michael K.

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Article abstract of DOI:10.1039/CC9960000961

Irradiation of [(η⁵-C₅H₅)Rh(PMe₃XC ₂H₄)] in pentafluoroanisole generates the metallacycle [(η⁵-C₅H₅)(PMe₃)RhCH ₂OC₆F₄]; reaction of this complex with 1 equiv. of Ph₃C⁺PF₆⁺ at 220 K generates [(η⁵-C₅H₅)(PMe₃)Rh=C(H)OC ₆F₄]PF₆.

Full text of DOI:10.1039/CC9960000961

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Product name:[Rh(C₅H₅)(P(C₆H₅)3)(C₆F₄OCH₂)]

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