Reactions in Solid and Constrained State. IV.(1a - C) Preparation and Solid-State Photoracemization of Optically Active Alkyl Cobaloxime Complexes

DOI: 10.1246/bcsj.71.1871

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1871 - 1886 (1998)

Update date:2022-07-29

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Authors:

Arai, Yoshifusa

Ohgo, Yoshiaki

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Article abstract of DOI:10.1246/bcsj.71.1871

Various optically active 1-substituted and 1,2-disubstituted ethyl cobaloxime [bis(dimethylglyoximato)cobalt(III)] complexes including deuterium-labeled complexes were prepared. Their photoracemization was found to occur upon irradiation of visible light

Full text of DOI:10.1246/bcsj.71.1871

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Product name:[(RS)-1,2-bis(ethoxycarbonyl)ethyl]bis(dimethylglyoximato)(dimethylphenylphosphine)cobalt(III)

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