Tandem synthesis of polypropionate chains-highly stereoselective synthesis of the ansa chain of streptovaricin U and protostreptovaricins based on stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminium

DOI: 10.1039/CC9960001027

Source and publish data:

Chemical Communications p. 1027 - 1028 (1996)

Update date:2022-08-04

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Authors:

Miyashita, Masaaki

Shiratani, Tomonori

Kawamine, Katsumi

Hatakeyama, Susumi

Irie, Hiroshi

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Article abstract of DOI:10.1039/CC9960001027

The highly stereoselective synthesis of the ansa chain segment 23 of streptovaricin U and protostreptovaricins (I and II) is achieved by stereospecific methylation of γ,δ-epoxy acrylates with trimethylaluminium.

Full text of DOI:10.1039/CC9960001027

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