Diastereoselective synthesis of heterosubstituted organogembismetallic reagents. Application to a new propargylmetalation reaction of vinyl metals

DOI: 10.1016/0040-4020(96)00248-7

Source and publish data:

Tetrahedron p. 7235 - 7250 (1996)

Update date:2022-07-30

Topics:

Authors:

Brasseur, Denis

Marek, Ilane

Normant, Jean-F.

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Article abstract of DOI:10.1016/0040-4020(96)00248-7

The allylzincation and propargylzincation of various γ-heterosubstituted vinyl metals proceed diastereoselectively. This represents a new synthetic approach to construct two or three adjacent stereogenic centers in acyclic systems.

Full text of DOI:10.1016/0040-4020(96)00248-7

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