Diastereoselective synthesis of heterosubstituted organogembismetallic reagents. Application to a new propargylmetalation reaction of vinyl metals

DOI: 10.1016/0040-4020(96)00248-7

Source and publish data:

Tetrahedron p. 7235 - 7250 (1996)

Update date:2022-07-30

Topics:

Authors:

Brasseur, Denis

Marek, Ilane

Normant, Jean-F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00248-7

The allylzincation and propargylzincation of various γ-heterosubstituted vinyl metals proceed diastereoselectively. This represents a new synthetic approach to construct two or three adjacent stereogenic centers in acyclic systems.

Full text of DOI:10.1016/0040-4020(96)00248-7

Products guided by the article

Product name:3-(N-benzyl)-amino-1-trimethylsilylbut-1-yne

Cas No:178391-26-9

R&D Labs maybe for 178391-26-9

Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Oceachem Group Limited

website:http://www.oceanchem-group.com

Contact:86-536-8596048

Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Sinoway International (Jiangsu) Co., Ltd.

Contact:+86-25-86630167

Address:17 Beijing Road (West), Nanjing, China
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG

Relevant to this article

Synthetic transmembrane channels: Functional characterization using solubility calculations, transport studies, and substituent effects

Doi:10.1021/ja962694a
(1997)
Photochemical conversion of the o-nitrobenzyl-C-glucoside to a sugar lactone

Doi:10.1016/j.carres.2011.10.027
(2011)
An efficient method for the synthesis of 3-mercapto-1-(1,3-thiazolin-2-YL)Azetidine useful for the pendant moiety of oral carbapenem, L-084

Doi:10.3987/COM-06-10810
(2006)
INDOLE-2,3-QUINODIMETHANES. SYNTHESIS OF INDOLOCARBAZOLES FOR THE SYNTHESIS OF THE FUSED DIMERIC INDOLE ALKALOID STAUROSPORINONE

Doi:10.1016/S0040-4020(01)88612-9
(1983)
Synthesis and biological evaluation of novel mono- and bivalent ASGP-R-targeted drug-conjugates

Doi:10.1016/j.bmcl.2017.12.032
(2018)
Metal-catalyzed [2+2+1] cycloadditions of 1,3-dienes, allenes, and CO

Doi:10.1002/anie.200600300
(2006)

Article Doi