Journal of the American Chemical Society p. 1992 - 1996 (1981)
Update date:2022-08-04
Topics:
Kerdesky, Francis A.
Ardecky, Robert J.
Lakshmikantham, M. V.
Cava, Michael P.
The anthracycline antibiotics daunorubicin and adriamycin are important clinically useful drugs in the treatment of a number of human cancers.The structurally simplified synthetic analogues 4-demethoxydaunorubicin and 4-demethoxyadriamycin show much clinical promise.The synthesis of the corresponding aglycon (+/-)-4-demethoxydaunomycinone from the inexpensive dye intermediate quinizarin, utilizing o-quinodimethane intermediates, is discussed.
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