Biosynthesis of tetronasin: Part 6. Preparation of structural analogues of the diketide and triketide biosynthetic precursors to tetronasin

DOI: 10.1016/0040-4039(96)00600-4

Source and publish data:

Tetrahedron Letters p. 3515 - 3518 (1996)

Update date:2022-08-03

Topics:

Authors:

Less, Simon L.

Handa, Sandeep

Millburn, Karen

Leadlay, Peter F.

Dutton, Christopher J.

Staunton, James

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Article abstract of DOI:10.1016/0040-4039(96)00600-4

The preparation of three analogues of the putative diketide biosynthetic precursor (2) and eight analogues of the putative triketide biosynthetic precursor (3) of the acyl tetronic acid ionophore tetronasin, as N-acetylcysteamine thioesters (4), (5), (6), (12), (13), (14), (15), (22), (23), (24) and (25) is described. Five examples are ¹⁹F-labelled; a new, enantiospecific method for the creation of a fluorinated quarternary α-centre is presented.

Full text of DOI:10.1016/0040-4039(96)00600-4

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