Tetrahedron Letters p. 3515 - 3518 (1996)
Update date:2022-08-03
Topics:
Less, Simon L.
Handa, Sandeep
Millburn, Karen
Leadlay, Peter F.
Dutton, Christopher J.
Staunton, James
The preparation of three analogues of the putative diketide biosynthetic precursor (2) and eight analogues of the putative triketide biosynthetic precursor (3) of the acyl tetronic acid ionophore tetronasin, as N-acetylcysteamine thioesters (4), (5), (6), (12), (13), (14), (15), (22), (23), (24) and (25) is described. Five examples are 19F-labelled; a new, enantiospecific method for the creation of a fluorinated quarternary α-centre is presented.
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