The kinetic influence of increasing steric hindrance to metallation by zinc (II) which accompanies the inclusion of 5,10,15,20-meso(tetraphenyl) porphyrin into capped and quadruply bridged closely spaced bis-porphyrin structures

DOI: 10.1016/0020-1693(95)04954-1

Source and publish data:

Inorganica Chimica Acta p. 195 - 202 (1996)

Update date:2022-08-03

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Authors:

Zhang, Hong-Yue

Bruice, Thomas C.

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Article abstract of DOI:10.1016/0020-1693(95)04954-1

The solvent system toluene:acetic acid:methanol = 5:20:75% (vol./vol.) has been developed for metallation of porphyrins. This system is quite suitable for kinetic studies because it affords stable homogeneous solutions of porphyrins plus metal salts. In t

Full text of DOI:10.1016/0020-1693(95)04954-1

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Product name:zinc(5,10,15,20)tetrakis(α-chloro-m-tolyl)porphyrin

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