Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1244 - 1246 (1992)
Update date:2022-08-03
Topics: Synthesis Yield Catalyst Nucleophilic addition Purification Chemical Reaction
Butenko, L. N.
Novakov, I. A.
Radchenko, S. S.
Kuznechikov, O. A.
Oglodina, T. Yu.
et al.
Via direct oxidative addition of 1,1-dichloroethylene to adamantane or 1,3-dimethyladamantane one obtains diethanoic acids of the adamantane series, which are useful in themselves or for preparation of other functional derivatives.Optimal reaction conditions were found by mathematical modeling.Keywords: synthesis, adamantane, dimethyladamantane, 1,1-dichloroethylene, 1,3-bis(carboxymethyl)adamantane, 1,3-bis(carboxymethyl)-5,7-dimethyladamantane, mathematical planning.
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