Chiral enol ethers in carbohydrate chemistry: De novo synthesis of protected L-2-deoxy hexoses

DOI: 10.1016/0040-4039(96)00769-1

Source and publish data:

Tetrahedron Letters p. 4007 - 4010 (1996)

Update date:2022-08-03

Topics:

Authors:

Dujardin

Rossignol

Brown Brown

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Article abstract of DOI:10.1016/0040-4039(96)00769-1

(3,4,6)Tri- and (3,4)-di-O-benzyl-2-deoxy-L-glucose 8 and 12 have been de novo synthesized in a convergent seven-step sequence involving asymmetric endo heterocycloaddition of the new heterodiene, methyl (E)-benzyloxymethylene pyruvate 2b with the O-vinyl mandelic ester (R)-(-)-3.

Full text of DOI:10.1016/0040-4039(96)00769-1

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