Tetrahedron p. 7435 - 7463 (1996)
Update date:2022-08-03
Topics:
Krief, Alain
Kenda, Benoit
Remacle, Bruno
2-Ethyl-1-methyl-1-phenyl cyclopentane, unavailable by butyllithium-promoted carbocyclisation of the corresponding alkenyl selenide, has been synthesized from 6-methylseleno-6-phenyl-1-phenylthio-1-heptene and 7-methylseleno-7-phenyl-2-phenylthio-2-octene with high stereocontrol at all the three stereogenic centers. Depending upon the solvent used, the derivative in which the methyl- and the phenylthiomethyl groups are cis (in THF) or trans (in pentane) to each other are formed selectively.
View MoreTaizhou KEDE Chemical.Co.,Ltd.
Contact:86-576-84613060
Address:Jiangkou Chemical Zoon
ShangHai Ruiyi Medical Technology Co.,Ltd.
Contact:+86-21-54718086
Address:No951 Jianchuan RD,Minhang District
Kunming Biohome Technology Co. Ltd.
website:http://www.biohometech.com/
Contact:86-871-67428869
Address:kunming
Contact:+65 9658 0999
Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
Contact:+86-021-58123769
Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Doi:10.1021/om9602015
(1996)Doi:10.1021/om960278t
(1996)Doi:10.1002/anie.201812348
(2019)Doi:10.1002/prac.19963380190
(1996)Doi:10.3762/bjoc.13.92
(2017)Doi:10.1021/jm00077a014
(1993)