Synthesis of alkynyl, cyclic carbene and vinylidene osmium(II) complexes: First indenyl half-sandwich osmium(II) complexes

DOI: 10.1039/dt9960002547

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2547 - 2551 (1996)

Update date:2022-08-03

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Authors:

Gamasa, M. Pilar

Gimeno, Jose

Gonzalez-Cueva, Mercedes

Lastra, Elena

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Article abstract of DOI:10.1039/dt9960002547

The reaction of [OsCl(η⁵-C₉H₇)(PPh₃) ₂] 1 with 3,3-dimethylbut-1-yne and NaPF₆ in refluxing methanol gave the vinylidene complex [Os{=C=C(H)Bu^t}(η⁵-C₉H View More

Full text of DOI:10.1039/dt9960002547

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Product name:[Os(CCC₅H₇)(C₉H₇)(P(C₆H₅)3)2]

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