
Polyhedron p. 2923 - 2926 (1996)
Update date:2022-08-04
Topics:
Bhawmick, Rupa
Bandyopadhyay, Pinaki
A number of stable di-μ-halogeno-bridged cyclopalladated complexes [Pd2L2Cl2] have been synthesized (where L = arylsulfides and their corresponding sulfoxides). The cyclopalladated compounds have been characterized on the basis of elemental analysis and spectroscopic (IR, UV-vis, and 1H and 13C NMR) data. Regioselective aromatic metaloxylation (Pd-Ar→Pd-O-Ar) or di-μ-halogeno-bridged cyclopalladated complexes occur with m-chloroperbenzoic acid at room temperature without any oxidation of sulfur atoms. Copyright
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Doi:10.1021/jo960438a
(1996)Doi:10.1016/0040-4020(96)00666-7
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(2013)Doi:10.1016/0022-328X(96)06279-1
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(1996)