Fragmentation of an imido tin(II) cubane; syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions

DOI: 10.1039/cc9960001501

Source and publish data:

Chemical Communications p. 1501 - 1502 (1996)

Update date:2022-08-02

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Authors:

Allan, Robert E.

Beswick, Michael A.

Cromhout, Natalie L.

Paver, Michael A.

Raithby, Paul R.

Steiner, Alexander

Trevithick, Mark

Wright, Dominic S.

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Article abstract of DOI:10.1039/cc9960001501

The reactions of the imido tin(II) cubane [SnNBu^t]₄ with 3 equiv. of [C₁₀H₇NHLi] (C₁₀H₇ = 1-naphthyl) and 6 equiv. of [C₆H₁₁PHLi] (C₆H₁₁ = cyclohexyl) produce [Li(thf)₄]⁺[(Bu^tN)(C₁₀H ₇N)₃Sn₃Li·thf] ^-·thf·PhMe 1 and [{Sn₂(PC₆H₁₁)₃}₂Li ₄·4thf]·2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.

Full text of DOI:10.1039/cc9960001501

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